Navegação por autor "HWANG, JIANN-YANG"

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  • IPEN-DOC 25634

    MUNHOZ JUNIOR, ANTONIO H.; GALHARDO, GUSTAVO F.; ORTEGA, FERNANDO dos S.; LIMA, NELSON B. de ; MORAES, DENISON A.; MIRANDA, LEILA F. de; VALENZUELA-DIAZ, FRANCISCO R.. Alpha-alumina synthesis using gamma-alumina powders. In: LI, BOWEN (Ed.); LI, JIAN (Ed.); IKHMAYIES, SHADIA (Ed.); ZHANG, MINGMING (Ed.); KALAY, YUNUS E. (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); SPENA, PASQUALE R. (Ed.); GOSWAMI, RAMASIS (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2019. p. 441-451, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-05749-7_44

    Abstract: Alpha-alumina is a ceramic material with applications as a biomaterial in femoral prostheses and teeth. The study of the influence of the precursor powder on the microstructure and mechanical properties of the alumina obtained is extremely important for the use of the same as biomaterials. Other applications of alpha-alumina industrially are in obtaining parts used at high temperatures and in chemically aggressive environments. Alpha-alumina can be synthesized from different raw materials resulting in ceramic products with different microstructures and consequently with diverse mechanical resistance. The synthesis of alpha-alumina pieces obtained from gamma-alumina powders was studied in order to verify the mechanical properties of the sintered material. The addition of graphene oxide in the gamma-alumina powder was also studied. To evaluate the mechanical strength of the obtained alpha-alumina specimens and to correlate the mechanical resistance with the precursor used in alpha-alumina synthesis it was used three -point bend strength testing.

    Palavras-Chave: aluminium oxides; aluminium compounds; graphene; oxides

  • IPEN-DOC 25622

    MONTEIRO, ALEX S. ; BARREIRA, DAILI A.S. ; SILVA, JAQUELINE S. ; OLIVEIRA, RENE R. ; VALENZUELA-DIAZ, FRANCISCO R.; MOURA, ESPERIDIANA A.B. . An investigation of mechanical and thermal properties of polypropylene reinforced with different clays. In: LI, BOWEN (Ed.); LI, JIAN (Ed.); IKHMAYIES, SHADIA (Ed.); ZHANG, MINGMING (Ed.); KALAY, YUNUS E. (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); SPENA, PASQUALE R. (Ed.); GOSWAMI, RAMASIS (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2019. p. 453-463, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-05749-7_45

    Abstract: Nowadays, environmental awareness and an increasing concern with the greenhouse effect have increased the interest in composite materials containing at least one of the components from natural origin. Natural clays seem to be a good alternative because they are environmentally acceptable, naturally abundant minerals, and due to their ability to intercalate and exfoliate in the polymer matrix led to an improvement in mechanical, thermal and barrier properties, compared to the neat polymer. This work presents an investigation of the effects of incorporation of two different clays on mechanical and thermal properties of polypropylene (PP) matrix. PP with 1.5–3.0 wt% of the Cloisite® (commercial clay), and light green clay (noncommercial Brazilian clay), was prepared by melt extrusion process. The neat PP and its nanocomposites were characterized by mechanical tests, SEM, DSC, TGA and XRD analyses. In addition, clay characterization by XRD has also been carried out.

    Palavras-Chave: polypropylene; clays; tensile properties; thermal gravimetric analysis

  • IPEN-DOC 27623

    KOMATSU, LUIZ G.H. ; OLIANI, WASHINGTON L. ; OLIVEIRA, CAMILA B. ; RANGARI, VIJAYA K.; PARRA, DUCLERC F. . Application of nanoparticles of ZnO and ZnO-doped-Ag in polymeric blend of HMSPP/SEBS for biocide activity. In: LI, JIAN (Ed.); ZHANG, MINGMING (Ed.); LI, BOWEN (Ed.); MONTEIRO, SERGIO N. (Ed.); IKHMAYIES, SHADIA (Ed.); KALAY, YUNUS E. (Ed.); HWANG, JIANN-YANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); CARPENTER, JOHN S. (Ed.); BROWN, ANDREW D. (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2020. p. 429-435, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-36628-5_41

    Abstract: In this study, the nanoparticles of Zinc oxide (ZnO) and Zinc oxide doped with Silver (ZnO/Ag) were synthesized in laboratory. The incorporation of these nanoparticles in the blend of high melt strength polypropylene (HMSPP) and styrene– ethylene/butadiene–styrene (SEBS) was carried by melt processing. The obtained materials were evaluated by X-ray diffraction (XRD), Raman Spectroscopy, Differential Scanning Calorimetry (DSC), biocidal tests against the bacteria Escherichia coli and Staphylococcus aureus. The nanoparticles showed size between 150 and 200 nm and spherical form. HMSPP/SEBS/AgNPs/ZnO films incorporated with the nanoparticles have demonstrated biocidal effect against the bacteria E. coli and S. aureus when irradiated at 12.5 kGy.

    Palavras-Chave: zinc oxides; antimicrobial agents; nanoparticles; antibiotics

  • IPEN-DOC 21510

    POVEDA, PATRICIA N.S. ; VIANA, HAMILTON M.; ANDRADE e SILVA, LEONARDO G. de . Behavior of linear low density polyethylene films under UV ageing for agricultural application. In: CARPENTER, JOHN S. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO, JUAN P. (Ed.); HWANG, JIANN-YANG (Ed.); LI, BOWEN (Ed.); LI, JIAN (Ed.); MONTEIRO, SERGIO N. (Ed.); PENG, ZHIWEI (Ed.); ZHANG, MINGMING (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 144th . ANNUAL MEETING & EXIBITION, March 15-19, 2015, Orlando, Florida. Proceedings... New York: Wiley , 2015, 2015. p. 253-258. DOI: 10.1002/9781119093404.ch31

    Palavras-Chave: polyethylenes; aging; films; films; infrared spectra; ultraviolet radiation; polymers; additives; sampling; agriculture

  • IPEN-DOC 27621

    COSTA, ROBSON S. ; MOURA, ESPERIDIANA A.B. . A bibliometric analysis of the strategy and performance measurement of the polymer matrix nanomaterials development scenario globally, and the participation of Brazil. In: LI, JIAN (Ed.); ZHANG, MINGMING (Ed.); LI, BOWEN (Ed.); MONTEIRO, SERGIO N. (Ed.); IKHMAYIES, SHADIA (Ed.); KALAY, YUNUS E. (Ed.); HWANG, JIANN-YANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); CARPENTER, JOHN S. (Ed.); BROWN, ANDREW D. (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2020. p. 329-342, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-36628-5_31

    Abstract: Extensive studies have been conducted worldwide on the strategy for the development of nanomaterials. One of the known strategies for this has aroused interest in the market is the incorporation of the nanoparticles, extracted from the residues in thematrices of the polymers for the production of environmentally correct nanocomposites. This work presents a survey of the scientific knowledge of nanomaterials of the polymer matrix and a panoramic view of the evolution of these nanomaterials are subject, in order to meet the criteria of sustainable development due to the environmental concerns. This study also intends to use bibliometric tools to database acquisition and analysis of bibliographic reviews for an evaluation of the scenarios in the world on the development of polymeric nanomaterials based on three different classes of polymeric nanocomposites: polymer/clay; polymer/graphene, and polymer/nanocellulose nanocomposites.

    Palavras-Chave: statistical data; nanomaterials; nanocomposites; scientific personnel; knowledge management; polymers

  • IPEN-DOC 20810

    LIMA, ROBERTA A. ; OLIVEIRA, RENE R. ; WATAYA, CELIO H. ; MOURA, ESPERIDIANA A.B. . Biodegradable starch/copolyesters film reinforced with silica nanoparticles: preparation and characterization. In: CARPENTER, JOHN S. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO, JUAN P. (Ed.); HWANG, JIANN-YANG (Ed.); LKHMAYIES, SHADIA (Ed.); LI, BOWEN (Ed.); LI, JIAN (Ed.); MONTEIRO, SERGIO N. (Ed.); PENG, ZHIWEI (Ed.); ZHANG, MINGMING (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 144th . ANNUAL MEETING & EXIBITION, March 15-19, 2015, Orlando, Florida. Proceedings... New York: Wiley , 2015, 2015. p. 687-693. DOI: 10.1002/9781119093404.ch87

    Palavras-Chave: nanostructures; composite materials; polymers; biodegradation; mechanical properties; calorimetry

  • IPEN-DOC 25635

    MUNHOZ JUNIOR, ANTONIO H.; PACHECO, CAROLINE V.; MELO, HENRIQUE T.T.S.; PERES, RENATO M.; SILVA, LEONARDO G. de A. e ; MIRANDA, LEILA F. de; ROMERO FILHO, MARCOS. Characterization of a composite of high-impact polystyrene, pseudoboehmite and graphene oxide. In: LI, BOWEN (Ed.); LI, JIAN (Ed.); IKHMAYIES, SHADIA (Ed.); ZHANG, MINGMING (Ed.); KALAY, YUNUS E. (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); SPENA, PASQUALE R. (Ed.); GOSWAMI, RAMASIS (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2019. p. 511-522, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-05749-7_51

    Abstract: The application of a composite material of pseudoboehmite, polystyrene and graphene oxide was studied. The present work is the synthesis and characterization of high-impact polystyrene (HIPS) nanocomposite, with pseudoboehmite (PSB) and graphene oxide. Pseudoboehmite particles with nanometric dimensions were obtained by sol-gel process. The composites were characterized by mechanical tests (tensile strength, flexural strength, Izod Impact, Shore D Hardness), thermal (Flow index, temperature of thermal deflection under load-HDT, Vicat softening temperature, differential tests thermal analyses and thermogravimetric analysis) and morphologically by Scanning Electron Microscopy (SEM). The results obtained were compared with HIPS matrix properties, without PSB and graphene oxide addition. From the thermal analyzes, composite samples showed higher decomposition temperatures compared to pure high-impact polystyrene especially in the thermogravimetric analysis results, showing a considerable increase in the temperature at which material decomposition begins (322 °C for pure high-impact polystyrene and 380 °C for the composite).

    Palavras-Chave: composite materials; polystyrene; graphene; oxides; nanocomposites; aluminium compounds

  • IPEN-DOC 25623

    MIRANDA, LEILA F. de; MUNHOZ JUNIOR, ANTONIO H.; MASSON, TEREZINHA J.; SILVA, LEONARDO G. de A. e ; FRIEHE, KARL. Characterization of antistatic packaging based on PET/rGO. In: LI, BOWEN (Ed.); LI, JIAN (Ed.); IKHMAYIES, SHADIA (Ed.); ZHANG, MINGMING (Ed.); KALAY, YUNUS E. (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); SPENA, PASQUALE R. (Ed.); GOSWAMI, RAMASIS (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2019. p. 523-534, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-05749-7_52

    Abstract: Package for electronic components is one that protects an electronic or electrical device against electrostatic discharge. Traditionally, antistatic packages are produced with polystyrene (PS) or polypropylene (PP) filled with carbon black. Recently, studies have been carried out successfully for the application of polyethylene terephthalate (PET) filled with carbon black. This work aimed to obtain and characterize nanocomposites based on PET filled with reduced graphene oxide (rGO) and compare its physicochemical properties with PET filled with carbon black and PP filled with carbon black used in anti-static packaging. PET compounds containing 0.1; 0.3; 0.5 and 0.7wt% reduced graphene oxide were obtained by the modified Hummers process from the graphite and reduced with hydrazine. The thermomechanical, electrical and morphological properties of the obtained compounds were determined. The results showed that the addition of reduced graphene oxide to PET causes an increase in the melt flow index, also increase the tensile strength and electrical conductivity. The addition of reduced graphene oxide promotes the decrease in the hardness and thermal resistance of the obtained nanocomposites. Nanocomposites based on PET containing 0.5wt% and 0.7wt% reduced graphene oxide can be used in the handling, transport and storage of electronic components since their mechanical, thermal and resistivity properties are satisfactory for this purpose.

    Palavras-Chave: nanocomposites; polyethylene terephthalate; graphene; oxides; packaging

  • IPEN-DOC 22194

    MUNHOZ JUNIOR, ANTONIO H.; ANDRADE e SILVA, LEONARDO G. de ; MIRANDA, LEILA F. de; ANDRADES, RAPHAEL C.. Characterization of gamma-alumina obtained from aged pseudoboehmites. In: IKHMAYIES, SHADIA (Ed.); LI, BOWEN (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); LI, JIAN (Ed.); FIRRAO, DONATO (Ed.); ZHANG, MINGMING (Ed.); PENG, ZHIWEI (Ed.); ESCOBEDO, JUAN P. (Ed.); BAI, CHENGUANG (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 145th . ANNUAL MEETING & EXIBITION, February 14-18, 2016, Nashville, Tennessee, USA. Proceedings... New York: Wiley , 2016, 2016. p. 779-785.

    Palavras-Chave: ceramics; adsorption; catalysis; nanoparticles; synthesis; sol-gel process; x-ray diffraction; scanning electron microscopy; differential thermal analysis; thermogravimetric analysis; adsorption isotherms

  • IPEN-DOC 27624

    MIRANDA, LEILA F. de; BARBOSA, ISABELLA T.F.; MASSON, TEREZINHA J.; MUNHOZ JUNIOR, ANTONIO H.; SILVA, LEONARDO G. de A. e ; GONÇALVES, ALEKSANDRA A.A.. Characterization of hydrogels for release of cosmetic assets containing nanoemulsions of mandellic acid in different concentrations of pseudoboehmite. In: LI, JIAN (Ed.); ZHANG, MINGMING (Ed.); LI, BOWEN (Ed.); MONTEIRO, SERGIO N. (Ed.); IKHMAYIES, SHADIA (Ed.); KALAY, YUNUS E. (Ed.); HWANG, JIANN-YANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); CARPENTER, JOHN S. (Ed.); BROWN, ANDREW D. (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2020. p. 477-489, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-36628-5_47

    Abstract: Hydrogel is a gel formed by a three-dimensional network of hydrophilic polymers that are used as advanced asset release systems with good biocompatibility. The use of ionizing radiation to obtain hydrogels promotes cross-linking with the concomitant sterilization of the hydrogels. Aiming at the release of the mandelic acid (an active cosmetic), hydrogels were prepared using different concentration of poly(N-vinyl-2-pyrrolidone) (PVP), poly(ethylene glycol) (PEG) and agar containing nanoparticles of the pseudoboehmite, mandelic acid and Palmarosa and Rosa Mosqueta oils nanoemulsions, submitted to irradiation dose of 25 kGy. Hydrogels containing 7.5 wt% PVP showed better absorption, slip, odor results, and those with 10 wt% PVP were found to be inadequate. Nanoemulsions were characterized by acidity, density and optical microscopy; hydrogels samples were put under isothermal dehydration with air entrainment and dehydration was examined as a function of time. The results showed that the composition of hydrogels is stable, and the increase of the concentration of pseudoboehmite in hydrogels sample containing Palmarosa oil suffers less dehydration and those containing the two oils showed an increase in dehydration. The hydrogels obtained with 7.5 wt% of PVP and 3 wt% of pseudoboehmite, Rosa Mosqueta vegetable oil and mandelic acid are most suitable to be used in cosmetic products.

    Palavras-Chave: hydrogels; mandelic acid; pvp; consumer products

  • IPEN-DOC 23653

    SOUZA, CLECIA M. ; SILVA, LEONARDO G. . Characterization of irradiated and non-irradiated rubber from automotive scrap tires. In: IKHMAYIES, SHADIA J. (Ed.); LI, BOWEN (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); LI, JIAN (Ed.); FIRRAO, DONATO (Ed.); ZHANG, MINGMING (Ed.); PENG, ZHIWEI (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); BAI, CHENGUANG (Ed.) TMS ANNUAL MEETING & EXHIBITION, 145th; CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS, February 14-18, 2016, Nashville, Tennessee, USA. Proceedings... Hoboken, New Jersey: John Wiley & Sons, Inc., 2016. p. 713-720. DOI: 10.1007/978-3-319-48210-1_90

    Abstract: The aim of this work was to characterize the samples of irradiated and non-irradiated rubber from automotive scrap tires. Rubber samples from scrap tires were irradiated at irradiation doses of 200, 400 and 600kGy in an electron beam accelerator. Subsequently, both the irradiated and non - irradiated samples werec haracterized by thermogravimetry (TG), differential scanning calorimetry (DSC), tensile strength mechanical test, and Fourier transform infrared (FTIR) spectrophotometry.

    Palavras-Chave: rubbers; irradiation; scrap; tires; acceleration; recycling

  • IPEN-DOC 21506

    CARDOSO, E.C.L. ; SCAGLIUSI, S.R. ; LUGAO, A.B. . Characterization of mechanical properties of PP/HMSPP blends with natural and synthetic polymers subjected to gamma-irradiation. In: CARPENTER, JOHN S. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO, JUAN P. (Ed.); HWANG, JIANN-YANG (Ed.); IKHMAYIES, SHADIA (Ed.); LI, BOWEN (Ed.); LI, JIAN (Ed.); MONTEIRO, SERGIO N. (Ed.); PENG, ZHIWEI (Ed.); ZHANG, MINGMING (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 144th . ANNUAL MEETING & EXIBITION, March 15-19, 2015, Orlando, Florida. Proceedings... New York: Wiley , 2015, 2015. p. 629-636.

    Palavras-Chave: gamma radiation; bagasse; mechanical properties; polypropylene; synthetic materials; polymers

  • IPEN-DOC 24662

    FRANCISCO, DANAE L. ; PAIVA, LUCILENE B. de; ALDEIA, WAGNER; LUGAO, ADEMAR B. ; MOURA, ESPERIDIANA A.B. . Characterization of non-covalently functionalized halloysite. In: LI, BOWEN (Ed.); LI, JIAN (Ed.); IKHMAYIES, SHADIA (Ed.); ZHANG, MINGMING (Ed.); KALAY, YUNUS E. (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); FIRRAO, DONATO (Ed.); BROWN, ANDREW (Ed.); BAI, CHENGUANG (Ed.); PENG, ZHIWEI (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); GOSWAMI, RAMASIS (Ed.); KIM, JEONGGUK (Ed.). Characterization of Minerals, Metals, and Materials. TMS. Cham, CZ, Switzerland: Springer International Publishing AG, 2018. p. 317-323, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-319-72484-3_34

    Abstract: The inorganic nanotube halloysite (HNT) is a promising type of natural occurring filler for polymers. Its characteristics, such as high aspect ratio (10–50), small size, and high strength (elastic modulus—140 GPa) suggest that HNTs have a potential use in high-performance polymer nanocomposites. Compared to other nanoclays and nanosilica the relatively low content of hydroxyl groups on their surfaces makes HNTs relatively hydrophobic, although, sometimes, this is not sufficient for guaranty a good interfacial adhesion in composite systems. Further hydrophobic treatment is required to improve HNTs compatibility with polymer matrixes, maximizing interfacial interactions. In the present study, different percentages of EPB (2,2-(1,2-ethene diyldi-4,1-phenylene) bisbenzoxazole) was used to perform a non-covalent functionalization of halloysite, based on electron transfer interactions. The functionalization is characterized by specific surface area (BET), thermogravimetric analysis (TG) and water/toluene extraction experiment.

    Palavras-Chave: nanotubes; silicate minerals; clays; benzoxazoles; thermal gravimetric analysis; toluene; polymers

  • IPEN-DOC 23649

    PAIVA, DOUGLAS A.; OLIVEIRA, RENE R. ; MAIA, WILSON da S.; AUAD, MARIA L.; RANGARI, VIJAYA K.; MOURA, ESPERIDIANA A.B. . Comparative study of the effects of cellulose nanowhiskers and microcrystalline cellulose addition as reinforcement in flexible films based on biopolymer blends. In: IKHMAYIES, SHADIA J. (Ed.); LI, BOWEN (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); LI, JIAN (Ed.); FIRRAO, DONATO (Ed.); ZHANG, MINGMING (Ed.); PENG, ZHIWEI (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); BAI, CHENGUANG (Ed.) TMS ANNUAL MEETING & EXHIBITION, 145th; CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS, February 14-18, 2016, Nashville, Tennessee, USA. Proceedings... Hoboken, New Jersey: John Wiley & Sons, Inc., 2016. p. 409-416. DOI: 10.1007/978-3-319-48210-1_51

    Abstract: The objective of this study is to compare the effects of the addition of cellulose nanowhiskers and microcrystalline cellulose on properties of flexible films based on biodegradablepolymer blends. Composite films containing 1 wt. % of microcrystalline cellulose and 1-2 wt.% of cellulose nanowhiskers were prepared by melt extrusion, using a twin screw extruder machine and blown extrusion process. The effects of the addition of cellulose nanowhiskers and microcrystalline cellulose on mechanical and thermal properties of biocomposite films were investigated by tensile tests, XRD, TG, DSC and FE-SEM analysis and the correlation between properties was discussed.

    Palavras-Chave: biodegradation; polymers; films; mechanical properties; whiskers; nanotechnology

  • IPEN-DOC 23861

    PEREIRA, AMANDA C.S. ; CHINELLATO, ANNE C.; SORIA, ALEJANDRA T.; ABREU, ANIBAL V.; DEL MASTRO, NELIDA L. ; MOURA, ESPERIDIANA A.B. . Comparative study of the sugarcane bagasse FIBER/HDPE composite properties using electron-beam and gamma radiation treatments. In: HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); BAI, CHENGGUANG (Ed.); CARPENTER, JOHN (Ed.); CAI, MINGDONG (Ed.); FIRRAO, DONATO (Ed.); KIM, BUOUNG-GON (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 141th; ANNUAL MEETING & EXIBITION, March 11-15, 2012, Orlando, Florida, USA. Proceedings... Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012. p. 403-410. DOI: 10.1002/9781118371305.ch48

    Abstract: This work presents a comparative study of the thermo-mechanical and morphological properties of sugarcane bagasse fiber/HDPE composite treated with electron-beam and gamma radiation. The composite samples obtained by extrusion and injection molding processes were irradiated at 50 and 90 kGy using either a 1.5 MeV electron beam accelerator or gamma irradiator EMI-9, at room temperature in presence of air. The irradiated and non-irradiated samples were submitted to mechanical and MFI tests, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), sol-gel analysis and X-Rays Diffraction (XRD) and the correlation between their properties was discussed. Improvement of the bagasse fiber/HDPE composite properties, using electron-beam or gamma radiation, was found.

  • IPEN-DOC 25624

    MONTEIRO, ALEX S. ; BARREIRA, DAILI A.S. ; BARTOLOMEI, SUELLEN S. ; OLIVEIRA, RENE R. ; MOURA, ESPERIDIANA A.B. de . Comparative study of the use of rice husk ashes and graphite as fillers in polypropylene matrix composites. In: LI, BOWEN (Ed.); LI, JIAN (Ed.); IKHMAYIES, SHADIA (Ed.); ZHANG, MINGMING (Ed.); KALAY, YUNUS E. (Ed.); CARPENTER, JOHN S. (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); BAI, CHENGUANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); SPENA, PASQUALE R. (Ed.); GOSWAMI, RAMASIS (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2019. p. 561-570, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-05749-7_56

    Abstract: In recent years, carbonaceous materials have been widely studied for polymer composite applications due to its capability to improve the engineering properties of the polymeric matrix. Among various carbonaceous fillers, carbon nanotube, graphene, and graphite promise to be a suitable reinforcement of polymers. Rice husk ash (RHA), a large residue rich in carbon and silica produced by the burning of rice husk offers also an immense potential as a carbonaceous filler for polymer composites on account of its lowcost, lowdensity, high strength and elastic modulus, no health risks, and renewability. This work aims at studying the effects of RHA and graphite as fillers in polypropylene (PP) matrix composites. The composites PP/RHA and PP/graphite were produced by melting extrusion process. The materials obtained were subjected to mechanical tests, XRD, TG, and FEG-SEM analyses. Comparison studies between neat PP properties and its composites were carried out.

    Palavras-Chave: matrix materials; polypropylene; mechanical properties; thermodynamic properties; carbonaceous materials

  • IPEN-DOC 20807

    CAMPOS, REJANE D. ; HOSUR, MAHESH; JEELANI, SHAIK; DIAZ, FRANCISCO R.V.; MOURA, ESPERIDIANA A.B. ; SEO, EMILIA S.M. . Comparison between bio-composite based green HDPE/Brasil nut shell fiber (BNSF) treated and non treated by electron-beam radiation. In: CARPENTER, JOHN S. (Ed.); BAI, CHENGUANG (Ed.); HWANG, JIANN-YANG (Ed.); LKHMAYIES, SHADIA (Ed.); LI, BOWEN (Ed.); MONTEIRO, SERGIO N. (Ed.); PENG, ZHIWEI (Ed.); ZHANG, MINGMING (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 143rd . ANNUAL MEETING & EXIBITION, February 16-20, 2014, San Diego, California. Proceedings... New York: Wiley , 2014, 2014. p. 475-482. DOI: 10.1002/9781118888056.ch55

    Palavras-Chave: composite materials; mechanical properties; morphology; brazil; nuts; fibers; electron beams

  • IPEN-DOC 27622

    SOARES, CARLOS ; SANTANA, JULYANA ; GUVEN, OLGUN; MOURA, ESPERIDIANA A.B. . A comparison between graphene oxide and reduced graphene oxide as reinforcement agents in polypropylene nanocomposite using irradiated polypropylene as compatibilizer. In: LI, JIAN (Ed.); ZHANG, MINGMING (Ed.); LI, BOWEN (Ed.); MONTEIRO, SERGIO N. (Ed.); IKHMAYIES, SHADIA (Ed.); KALAY, YUNUS E. (Ed.); HWANG, JIANN-YANG (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); CARPENTER, JOHN S. (Ed.); BROWN, ANDREW D. (Ed.). Characterization of Minerals, Metals, and Materials. Cham, CZ, Switzerland: Springer Nature Switzerland AG, 2020. p. 385-394, (The Minerals, Metals & Materials Series). DOI: 10.1007/978-3-030-36628-5_36

    Abstract: Graphene is thematerial with the bestmechanical resistance ever encountered. Various types of studies have been carried out on possible applications. The use as a reinforcement in nanocomposites has shown to be a promising field, but some studies indicate that the graphene oxide (GO) and reduced graphene oxide (RGO) have better results as reinforcement, due to the functional groups,which allowa better adhesion with the matrix. This study analyzes the production of polypropylene (PP) nanocomposite comparing the use of graphene oxide (GO) and reduced graphene oxide (RGO) as fillers and irradiated polypropylene as a coupling agent.Atwin-screw extruder and injection molding machine were used to produce the nanocomposite PP reinforced with 0.2 wt% of GO and RGO by melt blending. The GO and RGO were characterized byXRDanalysis.The nanocomposite sampleswere characterized by XRD, SEM, TG, DSC and mechanical test.

    Palavras-Chave: graphene; oxides; polypropylene; nanocomposites; gamma radiation; stresses; tensile properties

  • IPEN-DOC 23881

    ORTIZ, ANGEL ; ESCANHOELA, CORDELIA M.F. ; GOMES, MICHELLE ; OLIVEIRA, RENE R. ; DIAZ, FRANCISCO R.V.; MOURA, ESPERIDIANA A.B. . Comparison between HDPE/clay and HDPE/piassava fiber/clay treated by electron beam radiation. In: HWANG, JIANN-YANG (Ed.); BAI, CHENGGUANG (Ed.); CARPENTER, JOHN (Ed.); IKHMAYIES, SHADIA J. (Ed.); LI, BOWEN (Ed.); MONTEIRO, SERGIO N. (Ed.); PENG, ZHIWEI (Ed.); ZHANG, MINGMING (Ed.) CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS. 142th; ANNUAL MEETING & EXIBITION, March 3-7, 2013, San Antonio, Texas, USA. Proceedings... Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. p. 425-432. DOI: 10.1002/9781118659045.ch49

    Abstract: This work evaluates changes in morphological, mechanical and thermo-mechanical properties of electron-beam irradiated HDPE/nanoclay and HDPE/Piassava fiber/nanoclay. Material samples irradiated with 100 and 200 kGy using a 1.5 MeV electron beam accelerator (room temperature, presence of air) were submitted to tensile, flexural, and HDT tests. MFI, SEM and XRD analyses were carried out. Correlation between properties was discussed. Results showed that incorporation of piassava (Attalea funifera Mart) fiber and nanoclay, followed by irradiation represented significant gain in thermo-mechanical properties. Changes in surface morphology and reduction in MFI were observed. In conclusion, it may be claimed that the incorporation of piassava fiber in small size particles and nanoclay in the HDPE followed by electron-beam irradiation effectively improved the polymer properties and led to materials with superior properties suitable for several industrial applications.

  • IPEN-DOC 23237

    OLIANI, WASHINGTON L. ; PARRA, DUCLERC F. ; LIMA, LUIS F.C.P. ; OTAGURO, HARUMI; FERRETO, HELIO F.R. ; LUGAO, ADEMAR B. . Contribution to the β relaxation study of the HDPE, LDPE and LLDPE. In: IKHMAYIES, SHADIA (Ed.); LI, BOWEN (Ed.); CARPENTER, JOHN S. (Ed.); LI, JIAN (Ed.); HWANG, JIANN-YANG (Ed.); MONTEIRO, SERGIO N. (Ed.); FIRRAO, DONATO (Ed.); ZHANG, MINGMING (Ed.); PENG, ZHIWEI (Ed.); ESCOBEDO-DIAZ, JUAN P. (Ed.); BAI, CHENGUANG (Ed.); KALAY, YUNUS E. (Ed.); GOSWAMI, RAMASIS (Ed.); KIM, JEONGGUK (Ed.). Characterization of Minerals, Metals, and Materials. Gewerbestrasse, Switzerland: Springer International Publishing AG., 2017. p. 617-626, (The Minerals, Metals & Materials Series).

    Abstract: The activation of three polyethylenes, the low density, the high density and the linear low density polyethylene, was determined by means of dynamic mechanical analysis (DMA). Storage modulus and tan δ spectra were obtained as a function of the temperature from −60 to 50 °C with a heating rate of 2° min−1 at frequencies of 1, 2 and 5 Hz and measurement strain amplitude of 10−5. In the tan δ spectra, a small peak in the β region of the three polyethylenes was found and substantiated by subtracting the growing exponential background. This procedure was based on a model that associates the dislocation motion on metals under cyclic stress to vibrating strings and considering the same for the polymeric chains. For the determination of the activation energy we have utilized the frequency versus the reciprocal of the absolute temperature peak of the tan δ. The values obtained for the three polyethylenes, the low density, the high density and the linear low density were, 362 ± 12, 266 ± 9 and 197 ± 6 kJ mol−1, respectively, which were compared with those presented in the literature.

    Palavras-Chave: polyethylenes; relaxation; activation energy; density

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A elaboração do projeto do RI do IPEN foi iniciado em novembro de 2013, colocado em operação interna em julho de 2014 e disponibilizado na Internet em junho de 2015. Utiliza o software livre Dspace, desenvolvido pelo Massachusetts Institute of Technology (MIT). Para descrição dos metadados adota o padrão Dublin Core. É compatível com o Protocolo de Arquivos Abertos (OAI) permitindo interoperabilidade com repositórios de âmbito nacional e internacional.

O gerenciamento do Repositório está a cargo da Biblioteca do IPEN. Constam neste RI, até o presente momento 20.950 itens que tanto podem ser artigos de periódicos ou de eventos nacionais e internacionais, dissertações e teses, livros, capítulo de livros e relatórios técnicos. Para participar do RI-IPEN é necessário que pelo menos um dos autores tenha vínculo acadêmico ou funcional com o Instituto. Nesta primeira etapa de funcionamento do RI, a coleta das publicações é realizada periodicamente pela equipe da Biblioteca do IPEN, extraindo os dados das bases internacionais tais como a Web of Science, Scopus, INIS, SciElo além de verificar o Currículo Lattes. O RI-IPEN apresenta também um aspecto inovador no seu funcionamento. Por meio de metadados específicos ele está vinculado ao sistema de gerenciamento das atividades do Plano Diretor anual do IPEN (SIGEPI). Com o objetivo de fornecer dados numéricos para a elaboração dos indicadores da Produção Cientifica Institucional, disponibiliza uma tabela estatística registrando em tempo real a inserção de novos itens. Foi criado um metadado que contém um número único para cada integrante da comunidade científica do IPEN. Esse metadado se transformou em um filtro que ao ser acionado apresenta todos os trabalhos de um determinado autor independente das variáveis na forma de citação do seu nome.