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Navegação Eventos - Resumos por autor "VANTOMME, ANDRE"
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PEREIRA, LUCIANO F.
; MESTNIK-FILHO, JOSE
; CARBONARI, ARTUR
; CAVALCANTE, FABIO
; LEITE-NETO, OSMAR
.
First-principles calculations of the magnetic hyperfine field at Cd sites in RECd (RE = rare-earth element).
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
Binary magnetic compounds based on rare-earth (RE) elements of the type REX, where X is
a transition metal, with the simplest stoichiometry and crystalline cubic structure, are
isostructural systems with different RE constituents, which differ only slightly in the
crystallographic properties, but strongly in the magnetic properties. They thus offer
excellent conditions for the separation of the magnetic from other solid-state parameters
and permit the magnetism studies. However, in most RE compounds and, particularly when
X=Cd, details of the magnetic structure at an atomic scale are not available mainly because
is not possible to use neutron diffraction to investigate them. In this paper, the magnetic
hyperfine field (mhf) at Cd sites in RECd compounds was studied by first-principles
calculation. These compounds crystalizes in the CsCl prototype cubic structure (Pm-3m
space-group) and order ferromagnetically below the Curie temperature with exception of
PrCd, which presents antiferromagnetism. Recently, it was observed an unexpected
transition in the mhf at 111Cd in DyCd below 40 K, when mhf vanishes [1]. We have used the
density functional theory framework with full potential Augmented Planes Waves plus local
orbitals (APW+lo) method embodied in the WIEN2k code to simulate electronic structures
of the ferromagnetic and antiferromagnetic crystal cells in these compounds. For the
exchange-correlation effects we chose local density approximation. The mhf at Cd sites and
the formation energy were calculated for each compound as well as the density of states
were obtained. Results of mhf are in very good agreement (less than 10%) with the
experimental values previously reported [1]. Interestingly, for DyCd the energy for the
formation of the antiferromagnetic ordering with (π, π, 0) structure is smaller than that for
the ferromagnetic and others possible antiferromagnetic phases. As far as we know, it is
the first time that such an excellent agreement between the calculated and experimental
mhf at Cd sites is observed. Moreover, this results is even more important because the
calculations were fully variational without the use of the Hubbard model which takes into
account the on-site correlation of 4f electrons.
PEREIRA, LUCIANO F.; MESTNIK-FILHO, JOSE; CARBONARI, ARTUR; CAVALCANTE, FABIO; LEITE-NETO, OSMAR.
First-principles calculations of the magnetic hyperfine field at Cd sites in RECd (RE = rare-earth element).
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28084. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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KRYLOV, VASILY I.
; BOSCH-SANTOS, BRIANNA
; CABRERA-PASCA, GABRIEL A.
; CARBONARI, ARTUR W.
.
Huge negative magnetic hyperfine fields for 111Cd probe nuclei in the Fe3X (X=C, Ge, and Ga) compounds with specific properties.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
In recent years, Fe3X (X = C, Ga, and Ge) alloys are actively investigated experimental and
theoretical methods due to their potential practical use as invar, magnetostrictive
materials, and multi-layered ferromagnetic film [1-3]. The Fe3C alloy was studied by nuclear
resonant scattering on 57Fe and by x-ray emission spectroscopy at high pressure up to 50
GPa because this substance could be the major Earth’s inner core component [4, 5].
In this work we found huge negative HFs reaching a magnitude of Bhf = -46T on 111Cd probe
nuclei in ferromagnetic Fe3X (X = C, Ga, and Ge) alloys by perturbed γ-γ angular correlation
(PAC) spectroscopy. These values are the highest known HFs on 111Cd nuclei in metallic
magnets. It was established that in Fe3C crystallizing in the orthorhombic DO11 structure
(Pnma space group) 111Cd probes are placed in Feg sites with 11Fe atoms as nearest
neighbours (n.n.). For Feg positions, the n.n. arrangement is similar to normal hexagonal
close packing. The HF value for 111Cd atoms in Fe3C is equal to Bhf = -38.0(1) T at 77K. In
tetragonal DO3 crystal structure of Fe3Ga 111Cd probes are placed in both Ga sites (12 n.n.
Fe) and in FeII (8n.n.Fe). The HFs for 111Cd atoms in Fe3Ga are equal to Bhf = -39.8(1) T and
Bhf = -24.2(3) T at 77K for Ga and FeII sites of 111Cd localization. In hexagonal DO19 crystal
structure of Fe3Ge 111Cd probes are placed in Ge sites (12 n.n.). The HF value for 111Cd
probes in Fe3Ge is equal to Bhf = -46.0(1) T at 40K. There are no any anomalies of the Bhf (T)
on 111Cd nuclei in the spin reorientation region of Fe3Ge. The results of this work are
analyzed with the previously obtained HF’s values on 111Cd nuclei in 3d metals and their
alloys including Heusler alloys.
KRYLOV, VASILY I.; BOSCH-SANTOS, BRIANNA; CABRERA-PASCA, GABRIEL A.; CARBONARI, ARTUR W.
Huge negative magnetic hyperfine fields for 111Cd probe nuclei in the Fe3X (X=C, Ge, and Ga) compounds with specific properties.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28009. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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ANDRE-FILHO, J.; COAQUIRA, J.A.H.; MESTNIK-FILHO, J.
; CARBONARI, A.W.
; NAGAMINE, L.C.C.M..
Hydrogen absorption effects on the physical properties of ball-milled LaNiSn intermetallic compounds.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
A polycrystalline samples were prepared by arc melting high-purity elements under argon
atmosphere. The samples were re-melted several times to ensure homogeneity. After
arc-melting, the samples were annealed in vacuum at 800°C for 28h. After that, some
samples were milled using a Ball milling technique. The hydrogenation was carried out by
the Sievert’s method using a high purity hydrogen gas. X-ray diffraction (XRD)
measurements indicate the formation of the TiNiSi-type orthorhombic structure with space
group Pnma for the unmilled sample and its hydride. The milled samples show broad peaks
and poor crystallinity hindering the analysis of the structural properties. One sample was
milled with 10wt% of graphite. The analysis of the graphite-milled sample reveals that
graphite preserves the structural properties (the sample shows better crystalline quality)
and acts as a catalyst for the absorption of hydrogen. The analyses of the XRD patterns
show that the structural parameters are modified after the hydrogenation. The
transmission electron microscope images corroborate the XRD data. Mössbauer spectra
(297K) of the unmilled LaNiSn show the presence of only one doublet inconsistency with
the one symmetry site of Sn atoms in the TiNiSn-type structure. Moreover, spectra of the
milled samples are better reproduced by considering three doublets. Those components
were associated with Sn atoms occupying regular sites (D1), Sn atoms substituting Ni atoms
(D2) and Sn atoms of some spurious phase or Sn atoms localized in the interface region of
the grains (D3). The spectral area of the D1 component decreases at expenses of the other
two components. However, the isomeric shift (IS) of D1 and D2 shows a constant value as
the milling time is increased. The IS of the third doublet shows some fluctuating behavior
likely related to its small spectral area. The quadrupole splitting (QS) of D2 component
shows larger value than that of the D1 component and both show clear increasing tendency
as the milling time is increased. After the hydrogenation, the IS shows an increase related
to the samples before hydrogenation. However, the IS of the D1 and D2 components do not
undergo a drastic change in value with the milling time. The value of the QS of D1 and D2
components show an increase with the milling time. This result has been assigned to the
indirect interaction between Sn and H atoms which causes an asymmetric electron
distribution around the Sn atoms.
ANDRE-FILHO, J.; COAQUIRA, J.A.H.; MESTNIK-FILHO, J.; CARBONARI, A.W.; NAGAMINE, L.C.C.M.
Hydrogen absorption effects on the physical properties of ball-milled LaNiSn intermetallic compounds.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28011. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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DOMIENIKAN, CLAUDIO
; BOSCH-SANTOS, BRIANNA
; PASCA, GABRIEL A.C.
; SAXENA, RAJENDRA
; CARBONARI, ARTUR
.
Hyperfine field at La in the intermetallic compound LaMnSi2 measured by PAC using 140Ce nuclear probe.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
Magnetic hyperfine field has been measured in the orthorhombic intermetallic compound
LaMnSi2 with PAC spectroscopy using radioactive 140La-140Ce nuclear probes.
Magnetization measurement was also carried out in this compound with MPSM-SQUID
magnetometer. The LaMnSi2 sample was prepared by melting pure metallic components in
stoichiometric proportions in an arc furnace under argon atmosphere. After melting, the
sample was annealed at 1000 o C for 60h under helium atmosphere and then quenched in
to water. X-ray analysis confirmed the sample to be in a single phase with correct crystal
structure expected for LaMnSi2. The radioactive nuclei, 140La (T1/2 = 40h) were produced by
direct irradiation of the sample with neutrons in the IEA-R1 nuclear research reactor at
IPEN with a flux of ~1013 ncm-2s-1 for about 3-4 min. The irradiated sample was annealed
at 1000 o C under helium atmosphere for 24 hours before starting the PAC measurement in
order to minimize the effects of eventual radiation damage by fast neutrons during
irradiation as well as to allow the decay of the short lived 56Mn (T1/2 = 2.6h) activity also
produced in the sample. The PAC measurements were carried out with a six BaF2 detector
spectrometer at several temperatures between 10 K and 400 K. The results showed well
defined magnetic dipole interaction at all temperatures. Temperature dependence of the
hyperfine field, Bhf was found to be anomalous. The magnetization measurement however,
showed no anomaly. Therefore, the anomalous behavior of Bhf may be attributed to the
interaction where 1f electron of the dilute Ce atom is spin polarized by the magnetic field
from Mn sublattice and contributes to the effective hyperfine field. The ferromagnetic
transition temperature (TC) of LaMnSi2 was determined to be 400(1) K confirming by
magnetic measurement and the earlier results.
DOMIENIKAN, CLAUDIO; BOSCH-SANTOS, BRIANNA; PASCA, GABRIEL A.C.; SAXENA, RAJENDRA; CARBONARI, ARTUR.
Hyperfine field at La in the intermetallic compound LaMnSi2 measured by PAC using 140Ce nuclear probe.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28006. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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SILVA, ERIC B. da
; CORREIA, JOAO G.; ZOGHBY, MICHEL; GAHL, JOHN; SCHELL, JULIANA; MATOS, IZABELA T. de
; RIBEIRO JUNIOR, IBERE S.
; CARBONARI, ARTUR W.
; HUBLER, GRAHAM K.; VIOLANTE, VITTORIO; THIOYE, MOUSTAPHA; HE, JINGHAO.
Hyperfine interactions in Pd foils during D/H electrochemical loading.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
The Fleischmann and Pons Effect (FPE) is the appearance of anomalous excess heat during
electrolytic loading of hydrogen in metal. Although observed well above measurement
uncertainties [1] this effect still remains unexplained. Unlike previous studies where
hydrogen (H) was pre-loaded before Time Differential Perturbed Angular Correlations
(TDPAC) [2,3] was performed, this present work probes, at the nanoscopic scale, palladium
(Pd) samples during H and deuterium (D) loading in 0.1M LiOH or LiOD electrolyte.
Radioactive 181Hf (181Ta) was implanted at 80 keV (HISKP-Bonn) and experiments were
performed at the ISOLDE-CERN SSP laboratories after vacuum annealing to recover
implantation defects. An almost “flat” unperturbed PAC – R(t) spectrum was observed, as
expected for Hf/Ta atoms at cubic Pd sites with no remaining point defects in their vicinity.
Upon D loading the “flat” unperturbed R(t) spectrum changes to a characteristic
Gaussian-like EFG distribution, centered near zero EFG, due to the random distribution of D
atoms inside the Pd lattice. With increasing D concentration, the central value of the
distribution becomes nonzero, thus revealing that the Pd crystalline structure is relaxed
from cubic, consistent with the phase diagram for Pd hydrides. The data also shows that,
while being an impurity in the system under study, the Hf/Ta atoms do not trap nor
significantly interfere with the H/D atoms in the Pd lattice that would bias the present
studies. Thus, further experiments aimed at studying the FPE under external excitations are
envisaged.
SILVA, ERIC B. da; CORREIA, JOAO G.; ZOGHBY, MICHEL; GAHL, JOHN; SCHELL, JULIANA; MATOS, IZABELA T. de; RIBEIRO JUNIOR, IBERE S.; CARBONARI, ARTUR W.; HUBLER, GRAHAM K.; VIOLANTE, VITTORIO; THIOYE, MOUSTAPHA; HE, JINGHAO.
Hyperfine interactions in Pd foils during D/H electrochemical loading.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28005. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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CAVALCANTE, FABIO H. de M.; SALES, TATIANE S.N.
; DAY, TRAVIS; LEITE NETO, OSMAR F.S.
; PEREIRA, LUCIANO F.D.
; SAXENA, RAJENDRA N.
; CARBONARI, ARTUR W.
; MENONI, CARMEN.
Influence of oxygen atmosphere in the annealing of HfO2 thin films studied by perturbed angular correlation spectroscopy.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
The thin films of HfO2 have been grown by dual ion beam sputtering (DIBS) on transparent
quartz substrates (grade silica) and silicon wafers. The major benefits of the DIBS process
are the increased packing density of the deposited films which makes them more bulk-like,
the improved adhesion resulting from the mixing of the materials at the interfaces between
each layer, and the reduction of the high tensile stress in the layers. Deposition conditions
were adjusted to obtain polycrystalline as well as amorphous films. In this study the time
differential perturbed angular correlation (PAC) spectroscopy was used to study the
influence of oxygen atmosphere in the annealing of the HfO2 thin film. The PAC method is
based on the hyperfine interaction of nuclear moments of the probe with extra nuclear
magnetic fields or electric field gradients (EFGs). In the case of quadrupolar interaction, the
experimental measurement gives the quadrupolar frequency νQ with respective distribution
δ as well as the asymmetry parameter η of EFG. The presence of the 180Hf isotope in natural
hafnium allows the possibility of using 181Ta as a probe nucleus formed by irradiating the
samples with neutrons via 180Hf(n,γ)181Hf reaction. After irradiation, samples were annealed
in oxygen atmosphere at different temperatures. The γ-γ PAC measurements were then
carried out using a standard set up with four conical BaF2 detector scintillators with a time
resolution of 0.6 ns (FWHM). Results show a structural transition from monoclinic to
tetragonal in the annealed samples.
CAVALCANTE, FABIO H. de M.; SALES, TATIANE S.N.; DAY, TRAVIS; LEITE NETO, OSMAR F.S.; PEREIRA, LUCIANO F.D.; SAXENA, RAJENDRA N.; CARBONARI, ARTUR W.; MENONI, CARMEN.
Influence of oxygen atmosphere in the annealing of HfO2 thin films studied by perturbed angular correlation spectroscopy.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28085. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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SILVA, ANDREIA
; AMARAL, ANTONIO
; LAPOLLI, ANDRE
; SAXENA, RAJENDRA
; CARBONARI, ARTUR
.
Investigation of hyperfine interactions in immunoglobulin G with perturbed angular correlation spectroscopy using 111Cd.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
Hyperfine interaction parameters have been used to investigate physical properties of
biomolecules from different isotypes of immunoglobulins G (IgG1, IgG2a and IgG2b).
Immunoglobulin IgG1 induces a pattern of response type Th2 that corresponds to an
allergic immunological response, whereas immunoglobulin IgG2 induces a pattern of
response Th1 that corresponds to a cellular immunological response, suited for response
against parasites. Hyperfine interactions were measured by perturbed gamma-gamma
angular correlation (PAC) spectroscopy using 111In(111Cd) and 111mCd(111Cd) as probe nuclei.
The measurements were carried out for both the complete and fragmented molecules at
295 K and 77 K, and both static as well as dynamic interactions were observed. Results of
both measurements were used to calculate the rotational correlation time for each studied
molecule. The complete and fragmented molecules showed different dynamic interactions.
It was therefore conclude that the PAC technique is quite adequate for differentiating
between the isotypes of immunoglobulins as well as their dynamic behavior if adequate
nuclear probe is utilized with rigorous control of measuring conditions. The hyperfine
parameters obtained are related to the physical properties of each molecule in an attempt
to understand the difference in their biological function.
SILVA, ANDREIA; AMARAL, ANTONIO; LAPOLLI, ANDRE; SAXENA, RAJENDRA; CARBONARI, ARTUR.
Investigation of hyperfine interactions in immunoglobulin G with perturbed angular correlation spectroscopy using 111Cd.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28008. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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SALES, TATIANE
; CAVALCANTE, FABIO
; CABRERA-PASCA, GABRIEL
; PEREIRA, LUCIANO F.
; SAXENA, RAJENDRA
; CARBONARI, ARTUR
.
Investigation of Rare Earth (RE = La, Dy, and Er) doping of HfO2 by perturbed angular correlation spectroscopy.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
The hyperfine interactions at 181Hf(181Ta) probe nuclei in HfO2 samples doped with 5%
rare-earth (RE = La, Dy, and Er) elements were measured by perturbed angular correlation
(PAC) spectroscopy. Hafnium dioxide has been extensively studied as a potential alternative
to silicon dioxide as dielectric gate material in the silicon based
complementary-metal-oxide-semiconductors (CMOS) technology due to its high dielectric
constant and relatively high thermal stability with respect to silicon. The addition of RE to
HfO2 can suppress oxygen vacancies and promote a change in the crystal structure
increasing the dielectric permitivity. Samples were prepared using the sol-gel chemical
method, starting from very pure metals. The resulting powder of each sample was annealed
in air at 550 o C for 12 h. The crystal structures of samples were checked by X-ray
diffraction. Result revealed only a single phase corresponding to the monoclinic phase P
21/C of HfO2 for all samples. PAC spectra measured at room temperature were fitted with
two electric quadrupole interactions with different environments for all samples including a
pure HfO2. The major components (70-75%) were characterized by quadrupole
frequencies 𝜈𝑄 ∼ 790 MHz with a distribution around 6% and asymmetry parameter 𝜂 =
0.34 for Dy- and Er-doped samples. La-doped sample showed a slightly lower frequency
(𝜈𝑄 = 727 MHz) with larger asymmetry parameter (𝜂 = 0.43) for the major component.
The major components are ascribed to probe nuclei at regular monoclinic sites of HfO2. The
quadrupole frequency 𝜈𝑄 and asymmetry parameter 𝜂 for Dy- and Er-doped samples
agree well with those values reported in the literature [1]. The minor components were
characterized by 𝜈𝑄 ∼ 760 MHz with a distribution around 8% and asymmetry parameter
𝜂 = 0.75 for Dy- and Er-doped samples and 𝜈𝑄 = 783 MHz and 𝜂 = 0.61 for La-doped
HfO2. These values are quite different from those reported for pure sample [1], assigned to
probe nuclei near defects, and probably they are due to probe nuclei close to RE dopants,
which reduce the presence of defects.
SALES, TATIANE; CAVALCANTE, FABIO; CABRERA-PASCA, GABRIEL; PEREIRA, LUCIANO F.; SAXENA, RAJENDRA; CARBONARI, ARTUR.
Investigation of Rare Earth (RE = La, Dy, and Er) doping of HfO2 by perturbed angular correlation spectroscopy.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28007. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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SCHELL, JULIANA; CORREIA, JOAO G.M.; DEICHER, MANFRED; LUPASCU, DORU C.; VIANDEN, REINER; BARBOSA, MARCELO; CARBONARI, ARTUR
.
Studying after effects by gamma-gamma and electron-gamma perturbed angular correlations.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
Using electron-gamma perturbed angular correlations (PAC) experiments working
side-by-side with gamma-gamma PAC on the same isomeric transitions, besides structural
properties, additional information can be unambiguously obtained by following the
electronic recombination at the atomic shells and the neighbor atoms after the emission of
the conversion electron from the probe nuclei K, L, or M atomic shells. Such experiments
can be envisaged, as well, to clear out gamma-gamma PAC experiments where the probing
state is fed by electron capture decay. There, one K, L, M orbital electron is absorbed by a
proton creating a hole when the atomic number changes from Z to Z-1. This causes a severe
electronic rearrangement of the atomic shells accompanied by the emission of x-rays and
Auger electrons. The atom is left in a highly ionized state and the recombination time – fast
or slow – depending on the availability and mobility of host electrons determines if a
transient effect is observed within the lifetime of the nuclear state used for PAC. This is the
so called “after effect”, that if properly understood, can further contribute to learn about
the interaction of the impurity probe with the host, eventually observing ionized states and
determining electron mobility [1]. Illustrating this problematic we present and discuss in
this work the study of TiO2 doping [2] using different PAC isotopes (111In/111Cd, 181Hf/181Ta,
111mCd/111Cd, 117Cd/117In).
SCHELL, JULIANA; CORREIA, JOAO G.M.; DEICHER, MANFRED; LUPASCU, DORU C.; VIANDEN, REINER; BARBOSA, MARCELO; CARBONARI, ARTUR.
Studying after effects by gamma-gamma and electron-gamma perturbed angular correlations.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28086. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
Como referenciar este item
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KRYLOV, V.I.
; BOSCH-SANTOS, B.
; CABRERA-PASCA, G.A.
; CARBONARI, A.W.
; SAXENA, R.N.
; MESTNIK-FILHO, J.
.
Temperature anomalies of the hyperfine magnetic fields on 111Cd probe nuclei in ferro- and antiferromagnetic phases of the ordered FeRh alloys.
In: TEMST, KRISTIAAN (Ed.); VANTOMME, ANDRE (Ed.); COTTENIER, STEFAAN (Ed.); PEREIRA, LINO (Ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Abstract:
FeRh ordered alloy crystallizes in the bcc B2 structure [1], presents first order phase
transition from antiferromagnetic (AF) ordering at low temperature to ferromagnetic (F)
state above 350 K [2], and shows significant magnetocaloric effect near RT [3]. Recently,
FeRh alloy has also been considered as an interesting material for spintronics applications
[4].
In the AF state, FeRh has compensated AFII-type magnetic structure with μFe=3.3 μB and
μRh=0. In the F state of FeRh both Fe and Rh atoms have magnetic moments of μFe=3.2 μB
and μRh=0.9 μB, respectively [5]. The Fe – Rh compounds were studied by Mössbauer
spectroscopy (MS) on 57Fe [6, 7] and 119Sn probe nuclei [8].
In this work, we have, for the first time, investigated the HFs for 111Cd probe atoms in two
FeRh samples of different composition by perturbed γ-γ angular correlation (PAC)
spectroscopy in the range from 40 K to a temperature above the TC. The alloy Fe0.48Rh0.52 (A1
sample) is AF at low temperatures. At the temperature Tt = 345 K the first order phase
transition is observed, and this compound becomes F at the temperatures lower than TC =
685 K. The alloy Fe0.52Rh0.48 (A2 sample) is only ferromagnetic below TC = 800 K. It was
established that in both alloys 111Cd probes substitute only Fe ions.
The HFs values extrapolated to 0 K were found to be B1(0) =8.70(5) T and B2(0) =5.53(5) T
for AF and F ordering of A1 and A2 samples, respectively. The HF in the AF state is almost
60% higher than the HF in the F alloy. The dependences B1 (T) and B2 (T) show anomalous
behavior. At Tt = 345 K, phase transition AF-F is accompanied by a sharp decrease in the HF
at 111Cd probe nuclei. Earlier, an increase of the corresponding HFs was observed for 57Fe
atoms and 119Sn impurity atoms in the region of AF-F transition by MS in [6] and [8].
Analysis of B1(T) and B2(T) has allowed to obtain the temperature dependences of the
competing contributions BFe (T) and BRh (T) to the HFs on 111Cd probe nuclei in FeRh alloys.
KRYLOV, V.I.; BOSCH-SANTOS, B.; CABRERA-PASCA, G.A.; CARBONARI, A.W.; SAXENA, R.N.; MESTNIK-FILHO, J.
Temperature anomalies of the hyperfine magnetic fields on 111Cd probe nuclei in ferro- and antiferromagnetic phases of the ordered FeRh alloys.
In:
TEMST, KRISTIAAN (ed.); VANTOMME, ANDRE (ed.); COTTENIER, STEFAAN (ed.); PEREIRA, LINO (ed.) INTERNATIONAL CONFERENCE ON HYPERFINE INTERACTIONS AND THEIR APPLICATIONS,
July 3-8, 2016,
Leuven, Belgium.
Abstract...
Leuven, Belgium: Instituut voor Kern- en Stralingsfysica,
2016.
Disponível em: http://repositorio.ipen.br/handle/123456789/28010. Acesso em: $DATA.
Esta referência é gerada automaticamente de acordo com as normas do estilo IPEN/SP (ABNT NBR 6023) e recomenda-se uma verificação final e ajustes caso necessário.
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